EXPERIMENTAL GEOCHEMISTRY STUDY ON GOLD IN WATER-ROCK REACTION UNDER THERMAL FLUID SYSTEM AT MESO-LOW TEMPERATURE     

GU Li  DAI Ta-gen 《大地构造与成矿学(英文版)》2001,25(1)

Based on the knowing geochemical characteristics of wall rock in the Mobin gold deposit and composition of fluid inclusion in ore,water-rock experiments were carried out,important achievements are acquired as following: Gold is mainly derived from the ore-bearing wall rock,i,e.,a series of epimetamorphic clastic gritstone,sandy slate,and tuffaceous slate in the Wuqiang Banxi Formation,Wuqiangxi Group.In thermal system with middle-low temperature chlorine gold may be derived form stable complex ions,so it is quite important in gold metallogenic process.Sulphur and chlorine perform as the major negative ions throughout the gold activation and migration movement.The concentration of sulphur and chlorine ions,pH value and temperature are of deciding significance for gold activation,migration and precipitation.  相似文献   

Application of the photoacoustic method for characterization of natural galena (PbS)     

P. M. Nikolić  S. Ðurić  D. M. Todorović  D. Vasiljević-Radović  V. Blagojević  P. Mihajlović  J. Elazar  K. T. Radulović  A. I. Bojičić  D. Urošević 《Physics and Chemistry of Minerals》2001,28(1):44-51

Electron transport properties of single crystal and polycrystalline natural mineral galena (PbS) samples from the Trep?a mine, Yugoslavia, were determined using the photoacoustic frequency transmission technique. Their thermal diffusivity (D _T≈0.16 × 10^?5 m² s^?1), the coefficient of diffusion (D between 0.15×10^?2 0.16×10^?2 m² s^?1) and lifetime of the excess carrier (τ≈35 μs and the front and rear recombination velocity (s _g≈65.5 m s^?1 and s _b≈66.4 m s^?1, respectively), were calculated by comparing the experimental results and the theoretical photoacoustic amplitude and phase signals. The lattice parameter obtained by X-ray work was a?=5.936?Å. The free carrier concentration of these single-crystal samples was measured using the Hall method (N?=?3×10¹⁸ cm^?3). Measurements of the optical reflectivity of the same samples, as a function of wavelength, in the infrared and far infrared ranges, were performed. In the far infrared range a free electron plasma frequency was observed and numerically analyzed, using the least-squares fitting procedure. The values of optical parameters were calculated and the value of the free carrier concentration obtained by the Hall method was confirmed.  相似文献   

塔里木盆地岩石层热结构特征   总被引：39，自引：10，他引：39       下载免费PDF全文

王良书  李成 《地球物理学报》1996,39(6):794-803

在大地热流密度分布的基础上，研究了塔里木盆地中库尔勒－若羌和阿克苏－叶城两条剖面岩石层热结构特征．由岩石层Ｐ波速度分布转换成生热率剖面，用二维数值模型获得了岩石层热结构和热状态特征．结果表明，塔里木盆地壳幔边界温度的高低与其埋深密切相关．居里等温面深度大，地幔热流密度较低．岩石层厚度变化与其新生代期间挠曲过程密切相关．在岩石层温度分布基础上，确定了深部脆－韧性过渡带深度和岩石层屈服强度，表明塔里木盆地岩石层相对较冷，且具有刚性的地球动力学特征．  相似文献   

大陆岩石圈流变学研究   总被引：2，自引：1，他引：2  

索书田 《地质科技情报》1992,11(2):6-10

简单介绍了流变学的概念和两种基本研究方法,基于大陆岩石圈较大洋岩石圈有更为复杂的流变特征客观事实,指出研究大陆岩石圈流变学的重要性,并提出几个主要的研究方向和领域。  相似文献   

Permeability of stratified sands     

C. O. Okagbue 《Geotechnical and Geological Engineering》1995,13(3):157-168

Summary The permeability of graded sands was studied in the laboratory to determine the influence, if any, of stratification order on permeability (i.e. the position in which finer or coarser layers occur in the flow path). The evidence suggests that the order of stratification does not influence the order of magnitude of permeability of a sand. This order of magnitude is determined by the fine fraction of the sand. However, the order of stratification does have an influence on the finer details (i.e. variation within the same order of magnitude) of permeability. In this regard, an unsorted sand (all fractions mixed together) has the lowest permeability while a sorted one that has the fine fraction at the end of the sequence has the highest vertical permeability. It is also concluded that empirical formulae that use only the effective size, D ₁₀, to estimate permeability yield results that are comparable with those that incorporate sorting in their formulae. However, experimental results show that these formulae do not yield reliable results when used for more denser sands.  相似文献   

福建省西部大地热流值   总被引：2，自引：0，他引：2       下载免费PDF全文

熊亮萍  胡圣标 《地质科学》1993,28(1):96-101

根据福建省西部53个钻孔的实测地温数据和300多块岩石样品的实测热导率数据,计算了29个大地热流值,说明福建西部热流的平均值为74mW/m²,相当于中新生代活动区的热流值。  相似文献   

320矿床成因和找矿方向   总被引：1，自引：0，他引：1  

侯运秋  王清河  刘立钧 《铀矿地质》1993,(1)

320矿床的含矿土岩是一套强烈硅化(角)砾状和(角)砾质岩,是地洼初动期岩溶洞穴沉(堆)积岩——以钙屑岩为主的混杂陆源沉积岩,受硅化形成。硅化主要发育于岩溶沉积岩中,并波及它附近的地层。这一事件发生于地洼余动期初,形成于低温环境,硅来自沉积岩源,流体起源于大气降水。320矿床是一个硅化改造的古岩溶矿床,它与美国亚利桑那州的硅化溶解-塌陷角砾岩筒相同。这类矿床在华南碳酸盐岩地区找矿潜力很大。  相似文献   

High-temperature X-ray investigation of natural columbites     

S. C.?Tarantino  M.?ZemaEmail author  M.?Pistorino  M. C.?Domeneghetti 《Physics and Chemistry of Minerals》2003,30(10):590-598

Structural investigations at high temperature were carried out on natural columbite samples across the join Fe(Nb_0.95Ta_0.05)₂O₆–Mn(Nb_0.95Ta_0.05)₂O₆. The samples were preliminarily annealed to attain the complete cation-ordered state and avoid the superimposition of the effects of cation ordering during high-temperature studies. Unit-cell parameters of three columbites with different X_Fe content were measured at regular intervals in the temperature range 25–900 °C using single-crystal X-ray diffraction techniques. The crystal structures of completely ordered ferrocolumbite and manganocolumbite were also refined from intensity data collected at room temperature, 300 and 600 °C. Structural thermal expansion coefficients show positive, linear expansion of a, b, c lattice constants and cell volume. In general, slightly higher expansion occurs along a and c directions. However, anisotropy decreases sharply with decreasing Fe content. Reversibility of thermal expansion in the investigated temperature range was checked by high-temperature diffraction studies under heating-up and cooling-down conditions. Impurities do not play an important role in thermal expansion of columbites; expansion coefficients measured on two crystals of the same sample characterized by different Ti content are in fact almost identical. Structural changes with temperature essentially affect bond lengths: volumes of both A and B octahedral sites increase linearly with temperature, whereas interpolyhedral geometrical parameters do not vary significantly.  相似文献   

Characterization of beryl (aquamarine variety) from pegmatites of Minas Gerais,Brazil   总被引：2，自引：0，他引：2  

R. R. Viana  H. Jordt-Evangelista  G. Magela da Costa  W. B. Stern 《Physics and Chemistry of Minerals》2002,29(10):668-679

Eight samples of the beryl variety aquamarine were selected from four pegmatites in the Governador Valadares and Araçuaí regions in northeastern Minas Gerais State, Brazil. These samples were fully characterized by chemical analysis, infrared and UV-visible spectroscopy, thermal analyses, and high-temperature X-ray diffraction (from room temperature up to 800 °C). Several physical and chemical properties of beryl were found to depend on the amount of water and ions residing in the structural channels. The thermal expansion coefficients from room temperature to about 800 °C are temperature-independent, with αa ? ?3.2 × 10^?6 ° C^?1 and αc ? ?8.7 × 10^?6 ° C^?1. The contraction of both a and c unit-cell parameters with increasing temperature and the shift of the infrared band centered at about 1200 cm^?1 were tentatively ascribed to interactions between channel water and the silicate rings.The color of beryl seems to be dictated by the relative proportions of Fe³⁺ in the octahedralsites and of fe²⁺ in the channels. Thus, deep-blue samples have little Fe³⁺, whereas greener samples have more Fe³⁺ or less channel Fe²⁺.  相似文献   

Geochemistry of the thermal springs and fumaroles of Basse-Terre Island,Guadeloupe, Lesser Antilles     

Tatjana Brombach  Luigi Marini  Johannes C. Hunziker 《Bulletin of Volcanology》2000,61(7):477-490

 The purpose of this work was to study jointly the volcanic-hydrothermal system of the high-risk volcano La Soufrière, in the southern part of Basse-Terre, and the geothermal area of Bouillante, on its western coast, to derive an all-embracing and coherent conceptual geochemical model that provides the necessary basis for adequate volcanic surveillance and further geothermal exploration. The active andesitic dome of La Soufrière has erupted eight times since 1660, most recently in 1976–1977. All these historic eruptions have been phreatic. High-salinity, Na–Cl geothermal liquids circulate in the Bouillante geothermal reservoir, at temperatures close to 250  °C. These Na–Cl solutions rise toward the surface, undergo boiling and mixing with groundwater and/or seawater, and feed most Na–Cl thermal springs in the central Bouillante area. The Na–Cl thermal springs are surrounded by Na–HCO₃ thermal springs and by the Na–Cl thermal spring of Anse à la Barque (a groundwater slightly mixed with seawater), which are all heated through conductive transfer. The two main fumarolic fields of La Soufrière area discharge vapors formed through boiling of hydrothermal aqueous solutions at temperatures of 190–215  °C below the "Ty" fault area and close to 260  °C below the dome summit. The boiling liquid producing the vapors of the Ty fault area has δD and δ¹⁸O values relatively similar to those of the Na–Cl liquids of the Bouillante geothermal reservoir, whereas the liquid originating the vapors of the summit fumaroles is strongly enriched in ¹⁸O, due to input of magmatic fluids from below. This process is also responsible for the paucity of CH₄ in the fumaroles. The thermal features around La Soufrière dome include: (a) Ca–SO₄ springs, produced through absorption of hydrothermal vapors in shallow groundwaters; (b) conductively heated, Ca–Na–HCO₃ springs; and (c) two Ca–Na–Cl springs produced through mixing of shallow Ca–SO₄ waters and deep Na–Cl hydrothermal liquids. The geographical distribution of the different thermal features of La Soufrière area indicates the presence of: (a) a central zone dominated by the ascent of steam, which either discharges at the surface in the fumarolic fields or is absorbed in shallow groundwaters; and (b) an outer zone, where the shallow groundwaters are heated through conduction or addition of Na–Cl liquids coming from hydrothermal aquifer(s). Received: 9 November 1998 / Accepted: 15 July 1999  相似文献